Morphological transformation of soot: investigation of microphysical processes during the condensation of sulfuric acid and limonene ozonolysis product vapors

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Creator/Principal investigator(s)

University of Gothenburg, Department of Chemistry & Molecular Biology

Ravi Kant Pathak

Description

The morphological transformation of soot particles via condensation of low-volatility materials constitutes a dominant atmospheric process with serious implications for the optical and hygroscopic properties, and atmospheric lifetime of the soot. We consider the morphological transformation of soot aggregates under the influence of condensation of vapors of sulfuric acid, and/or limonene ozonolysis products. This influence was systematically investigated using a Differential Mobility Analyzer-Aerosol Particle Mass Analyzer (DMA-APM) and the Tandem DMA techniques integrated with a laminar flow-tube system. We hypothesize that the morphology transformation of soot results (in general) from a two-step process, i.e., (i) filling of void space within the aggregate; (ii) growth of the particle diameter. Initially, the transformation was dominated by the filling process followed by growth, which led to the accumulation of sufficient material that exerted surface forces, which eventually facilitating further filling. The filling of void space was constrained by the initial morphology of the fresh soot

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Responsible department/unit

University of Gothenburg

Creator/Principal investigator(s)

University of Gothenburg, Department of Chemistry & Molecular Biology

Ravi Kant Pathak

Identifiers

SND-ID: SND 1057

Description

The morphological transformation of soot particles via condensation of low-volatility materials constitutes a dominant atmospheric process with serious implications for the optical and hygroscopic properties, and atmospheric lifetime of the soot. We consider the morphological transformation of soot aggregates under the influence of condensation of vapors of sulfuric acid, and/or limonene ozonolysis products. This influence was systematically investigated using a Differential Mobility Analyzer-Aerosol Particle Mass Analyzer (DMA-APM) and the Tandem DMA techniques integrated with a laminar flow-tube system. We hypothesize that the morphology transformation of soot results (in general) from a two-step process, i.e., (i) filling of void space within the aggregate; (ii) growth of the particle diameter. Initially, the transformation was dominated by the filling process followed by growth, which led to the accumulation of sufficient material that exerted surface forces, which eventually facilitating further filling. The filling of void space was constrained by the initial morphology of the fresh soot

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Language

English

Geographic spread

Geographic location: Sweden

Keywords

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Publications

Cheng Wu, Dui Wu, and Jian Zhen Yu. Quantifying black carbon light absorption enhancement with a novel statistical approach. Atmos. Chem. Phys., 18, 289–309, 2018. FranzKanngießer, MichaelKahnert. Calculation of optical properties of light-absorbing carbon with weakly absorbing coating: A model with tunable transition from film-coating to spherical-shell coating. J. Quant. Spectrosc. Radiat. Transfer, 216, 17–36, 2018.

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Version 1.0

Soot particle mobility-mass relationship measurement

Suggested citation

Ravi Kant Pathak, University of Gothenburg, Department of Chemistry & Molecular Biology. University of Gothenburg (2018). <em>Soot particle mobility-mass relationship measurement</em>. Swedish National Data Service. Version 1.0. <a href="https://doi.org/10.5878/mc9m-j176">https://doi.org/10.5878/mc9m-j176</a>

Creator/Principal investigator(s)

University of Gothenburg, Department of Chemistry & Molecular Biology

Ravi Kant Pathak

Description

Data is collected by instrument Differential Mobility Analyzer-Aerosol Particle Mass Analyzer (DMA-APM), program based on LabVIEW is used to control the instrument and log the data.

Data format / data structure

Numeric

Published: 2018-07-03
Last updated: 2018-08-14